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11.
《International Journal of Hydrogen Energy》2022,47(71):30494-30502
Metal-organic frameworks (MOFs) have emerged as efficient electrocatalysts due to the features of high specific surface area, rich pore structure and diversified composition. It is still challenging to synthesize self-supporting MOF-based catalysts using simple and low-cost fabrication methods. Herein, we successfully fabricated Ni-doped MIL-53(Fe) supported on nickel-iron foam (Ni-MIL-53(Fe)/NFF) as efficient electrocatalyst. A facile two-step solvothermal method without adding any metal salts was used, which can simplify the fabrication process and reduce the experimental cost. In the fabrication process, the bimetallic Ni-MIL-53(Fe)/NFF was in situ converted from an intermediate NiFe2O4/NFF. The obtained material exhibits outstanding electrocatalytic oxygen evolution performance with a low overpotential of 248 mV at 50 mA cm?2, and a small Tafel slope of 46.4 mV dec?1. This work sheds light on the simple and efficient preparation of bimetallic MOF-based material, which is promising in electrocatalysts. 相似文献
12.
《International Journal of Hydrogen Energy》2022,47(65):27973-27985
Metal-support interaction and catalyst pretreatment are important for industrial catalysis. This work investigated the effect of supports (SiO2, CeO2, TiO2 and ZrO2) for Cu–Pd catalyst with high Cu/Pd ratio (Cu/Pd = 33.5) regarding catalyst cost, and the reduction temperatures of 350 °C and 550 °C were compared. The activity based on catalyst weight follows the order of Si > Ce > Zr > Ti when reduced at 350 °C. The reduction temperature leads to the surface reconstruction over the SiO2, CeO2 and TiO2 catalysts, while results in phase transition over Cu–Pd/ZrO2. The effect of reduction temperature on catalytic performance is prominent for the SiO2 and ZrO2 supported catalysts but not for the CeO2 and TiO2 ones. Among the investigated catalysts, Zr-350 exhibits the highest methanol yield. This work reveals the importance of the supports and pretreatment conditions on the physical-chemical properties and the catalytic performance of the Cu–Pd bimetallic catalysts. 相似文献
13.
《中国稀土学报(英文版)》2022,40(8):1232-1237
Revealing the active species of the catalyst is conducive to the design of more efficient catalyst. Herein, we tried to demonstrate the roles of amorphous and crystalline structures on CePO4 catalyst during selective catalytic reduction (SCR) of NOx by NH3. Higher calcination temperature promotes the transfer of amorphous structure to crystalline structure on the surface of CePO4. Both amorphous and crystalline CePO4 species on CePO-X samples can provide acid sites for NH3 adsorption, but the former can provide more acid sites. The superior redox property of surface amorphous CePO4 species contributes to its high NH3-SCR activity at low temperature, but it also leads to the decrease of high temperature (>350 °C) NH3-SCR activity due to the oxidation of NH3. In contrast, crystalline CePO4 species shows high activity only at high temperature because of its poor redox property. Therefore, it can be inferred that amorphous and crystalline structures on CePO4 catalyst can be the efficient active species of NH3-SCR at low and high temperature, respectively. 相似文献
14.
《Journal of the European Ceramic Society》2022,42(3):913-920
Ceramic design based on reducing friction and wear-related failures in moving mechanical systems has gained tremendous attention due to increased demands for durability, reliability and energy conservation. However, only few materials can meet these requirements at high temperatures. Here, we designed and prepared a Sn-containing Si3N4-based composite, which displayed excellent tribological properties at high temperatures. The results showed that the friction coefficient and wear rate of the composites were reduced to 0.27 and 4.88 × 10?6 mm3 N?1 m?1 in air at 800 °C. The wear mechanism of the sliding pairs at different temperatures was revealed via detailed analyses of the worn surfaces. In addition, the tribo-driven graphitization was detected on the wear surfaces and in the wear debris, and the carbon phase was identified by SEM, TEM, and Raman spectrum. 相似文献
15.
Prashant Thapliyal Alok S. Kandari Vijendra Lingwal N.S. Panwar G. Mohan Rao 《Ceramics International》2021,47(9):12066-12071
(Ta2O5)1-x- (TiO2)x (TTOx) thin films, with x = 0, 0.03, 0.06, 0.08, and 0.11, were deposited using magnetron direct current (DC) sputtering method onto the P/boron-silicon (1 0 0) substrates by varying areas of Tantalum and Titanium metallic targets, in oxygen environment at ambient temperature. The as-deposited thin films were annealed at temperatures ranging from 500 to 800 °C. Generally, the formation of the Ta2O5 structure was observed from the X-ray diffraction measurements of the annealed films. The capacitance of prepared metal– oxide– semiconductor (MOS) structures of Ag/TTOx/p-Si was measured at 1 MHz. The dielectric constant of the deposited films was observed altering with varying composition and annealing temperature, showing the highest value 71, at 1 MHz, for the TTOx films, x = 0.06, annealed at 700 °C. With increasing annealing temperature, from 700 to 800 °C, the leakage current density was observed, generally decreasing, from 10?5 to 10?8 A cm?2, for the prepared compositions. Among the prepared compositions, films with x = 0.06, annealed at 800 °C, having the observed value of dielectric constant 48, at 1 MHz; and the leakage current density 2.7 × 10?8 A cm?2, at the electric field of 3.5 × 105 V cm?1, show preferred potential as a dielectric for high-density silicon memory devices. 相似文献
16.
At present, the synthesis of body temperature triggering shape memory polymers usually requires elaborate structural design, which limits their wide application. Herein, starting from bio-based Eucommia ulmoides gum (EUG), a series of EUG/silica hybrids (ESHs) are prepared through a facile one-pot process, in which EUG is epoxied and then self-crosslinked with SiO2 by epoxy ring-open reaction. Varying the amount of H2O2, the shape memory transition temperature (Ttrans) of ESHs is adjusted to 47.4–36.6 ℃, which is close to human body temperature (37 ℃). Among them, ESH-17 exhibited the best body temperature triggering shape memory ability (Ttrans = 36.6 ℃), which can restore the permanent shape within 60 s at 37 ℃ with a shape fixity ratio of 99% and shape recovery ratio near 100%. In addition, the shape memory mechanism is discussed and shows some application scenarios of ESHs. The as-produced materials can be used as smart biomaterials such as self-tightening sutures, self-sealing root canal filling materials, and so on. 相似文献
17.
《中国有色金属学会会刊》2021,31(8):2468-2478
An acoustic emission (AE) experiment was carried out to explore the AE location accuracy influenced by temperature. A hollow hemispherical specimen was used to simulate common underground structures. In the process of heating with the flame, the pulse signal of constant frequency was stimulated as an AE source. Then AE signals received by each sensor were collected and used for comparing localization accuracy at different temperatures. Results show that location errors of AE keep the same phenomenon in the early and middle heating stages. In the later stage of heating, location errors of AE increase sharply due to the appearance of cracks. This provides some beneficial suggestions on decreasing location errors of structural cracks caused by temperature and improves the ability of underground structure disaster prevention and control. 相似文献
18.
Zhencai Li Dacheng Zhou Lars R. Jensen Jianbei Qiu Yanfei Zhang Yuanzheng Yue 《Journal of the American Ceramic Society》2021,104(9):4471-4478
The transparent Er3+-Yb3+-doped fluoro-aluminosilicate glass-ceramic (GC) was prepared by melt-quenching. The crystal phase, morphology, and up-conversion (UC) luminescence of as-produced GC were characterized by X-ray diffraction, scanning electron microscopy, and fluorescence spectrophotometry, respectively. The results show that BaYF5 nanocrystals were uniformly distributed in the glass matrix of the as-produced GC. When the as-produced GC was subjected to heat treatment, the crystallinity was increased, but the crystal identity remains unchanged. Such heat-treatment doubled the intensity of the UC luminescence, and this enhancement was ascribed to the increased incorporation of both Er3+ and Yb3+ ions into the lower phonon energy environment of BaYF5 nanocrystals. Furthermore, the heat-treated GC was stable against further crystallization, and consequently its UC luminescence was stable at the application temperature. The heat-treated GC was found to possess an outstanding temperature-sensing capability. 相似文献
19.
本文开发了一种新型的方舱夹芯板用室温固化高强度环氧结构胶黏剂,验证了其物化特性、相关力学性能和环境适应性。结果表明此胶黏剂具有优良性能,可以满足方舱用大板胶黏剂的使用需求。 相似文献
20.
Coline Grisotto Janice Taïl Cynthia Planesse Nicolas Diotel Marie-Paule Gonthier Olivier Meilhac David Couret 《International journal of molecular sciences》2021,22(9)
Background: Stroke in context of type 2 diabetes (T2D) is associated with a poorer outcome than in non-diabetic conditions. We aimed at creating a new reproducible mouse model of stroke in impaired glucose tolerance conditions induced by high-fat diet. Methods: Adult C57BL6 mice were fed for 2 months with either normal diet (ND) or high-fat diet (HFD). We used a model of Middle Cerebral Artery Occlusion (MCAO) for 90 min. Oral Glucose Tolerance Test (OGTT) and Insulin Tolerance Test (ITT) were used to assess pre-diabetic status. Brain infarct volume, hemorrhagic transformation (HT) as well as systemic and cerebral inflammatory markers were evaluated. Results: HFD was associated with an increased body weight and glycemia following OGTT. The HFD group presented a significant increase in brain infarct volume (38.7 (IQR 30–46.7%) vs. 28.45 (IQR 21–30%); p = 0.016) and HT (HFD: 2 (IQR 1–5) vs. ND: 0 (IQR 0–1); p = 0.012) and higher levels of IL-6 and MCP-1 in infarcted hemisphere compared to the ND group. Conclusion: Two months of HFD in adult mice were sufficient to alter the lipid profile and the control of hyperglycemia. These metabolic perturbations were significantly associated with increased infarct volume and hemorrhagic complications. 相似文献